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Journal Articles

Removal and recovery of uranium from solid wastes by supercritical carbon dioxide fluid leaching method

Meguro, Yoshihiro; Tomioka, Osamu; Imai, Tomoki*; Fujimoto, Shigeyuki*; Nakashima, Mikio; Yoshida, Zenko; Honda, Tadashi*; Koya, Fumio*; Kitamura, Nobu*; Wada, Ryutaro*; et al.

Proceedings of International Waste Management Symposium 2004 (WM '04) (CD-ROM), 8 Pages, 2004/03

Supercritical CO$$_{2}$$ fluid leaching (SFL) method using supercritical CO$$_{2}$$ fluid containing a complex of HNO$$_{3}$$ - tri-n-butyl phosphate (TBP) was applied to removal of uranium from radioactive solid wastes. Sea sands, incineration ashes and porous alumina bricks were employed as matrixes of simulated solid wastes. Real radioactive incineration ash wastes and firebrick wastes were also subjected to the SFL treatment. It was found that uranium could be efficiently removed from both of the simulated wastes and real wastes by the SFL method. The removal efficiency of uranium from the real waste was lower than that from the corresponding artificial waste. About 1 g and 35 mg of uranium were recovered from 10 g of the real ash waste and 37 g of the real firebrick waste, respectively.

Journal Articles

Recovery of alkali salt by supercritical fluid leaching method using carbon dioxide

Watanabe, Takeshi*; Tsushima, Satoru*; Yamamoto, Ichiro*; Tomioka, Osamu; Meguro, Yoshihiro; Nakashima, Mikio; Wada, Ryutaro*; Nagase, Yoshiyuki*; Fukuzato, Ryuichi*

Proceedings of 2nd International Symposium on Supercritical Fluid Technology for Energy and Environment Applications (Super Green 2003), p.363 - 366, 2004/00

Recovery of salts by supercritical fluid leaching (SFL) method using carbon dioxide was experimentally studied. It was confirmed that LiCl was recovered with a mixed fluid of carbon dioxide and methanol, and KCl and SrCl$$_2$$ were recovered with a mixed fluid of carbon dioxide, methanol and crown ether. The influence of crown ether for KCl and SrCl$$_2$$ extraction were found to increase in the order of 15-crown-5 (15C5) $$<$$ 18-crown-6 (18C6) $$<$$ dicychlohexyl-18-crown-6 (DC18C6). It is expected that other salts can be recovered selectively with a mixed fluid of carbon dioxide, methanol and suitable crown ether.

Journal Articles

Development of radioactive waste treatment by Supercritical Fluid Leaching (SFL) method

Nagase, Yoshiyuki*; Masuda, Kaoru*; Wada, Ryutaro*; Yamamoto, Ichiro*; Tomioka, Osamu; Meguro, Yoshihiro; Fukuzato, Ryuichi*

Proceedings of 2nd International Symposium on Supercritical Fluid Technology for Energy and Environment Applications (Super Green 2003), p.254 - 257, 2004/00

no abstracts in English

Journal Articles

Extraction of uranium(VI) and lanthanide(III) ions into supercritical carbon dioxide fluid containing $$beta$$-diketone and tributylphosphate

Meguro, Yoshihiro; Iso, Shuichi; Ogiyanagi, Jin; Yoshida, Zenko

Analytical Sciences (CD-ROM), 17(Suppl.), p.721 - 724, 2002/03

no abstracts in English

Journal Articles

Effect of U(VI) concentration on equilibrium and kinetics in flow-extraction of U(VI) in HNO$$_{3}$$/supercritical CO$$_{2}$$+TBP system

Meguro, Yoshihiro; Iso, Shuichi; Yoshida, Zenko

Proceedings of International Solvent Extraction Conference 2002 (CD-ROM), p.1131 - 1136, 2002/00

no abstracts in English

Journal Articles

New method for the removal of uranium from solid wastes with supercritical CO$$_{2}$$ medium containing HNO$$_{3}$$-TBP complex

Tomioka, Osamu*; Meguro, Yoshihiro; Iso, Shuichi; Yoshida, Zenko; Enokida, Yoichi*; Yamamoto, Ichiro*

Journal of Nuclear Science and Technology, 38(6), p.461 - 462, 2001/06

 Times Cited Count:27 Percentile:85.67(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Modelling of the extraction of uranium with supercritical carbon dioxide

Clifford, A. A.*; Zhu, S.*; Smart, N. G.*; Lin, Y.*; Wai, C. M.*; Yoshida, Zenko; Meguro, Yoshihiro; Iso, Shuichi

Journal of Nuclear Science and Technology, 38(6), p.433 - 438, 2001/06

 Times Cited Count:14 Percentile:68.91(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Supercritical fluid extraction

Meguro, Yoshihiro

Bunseki, 2001(4), p.187 - 188, 2001/04

no abstracts in English

Journal Articles

Separation of metals using supercritical carbon dioxide as extraction medium

Meguro, Yoshihiro; Yoshida, Zenko

Bunseki, 1999(11), p.922 - 929, 1999/00

no abstracts in English

Journal Articles

Solubility of organophosphorus metal extractants in supercritical carbon dioxide

Meguro, Yoshihiro; ; Sasaki, Takayuki*; Yoshida, Zenko

Analytical Chemistry, 70(4), p.774 - 779, 1998/02

 Times Cited Count:71 Percentile:91.7(Chemistry, Analytical)

no abstracts in English

Journal Articles

Correlation between extraction equilibrium of uranium(VI) and density of CO$$_{2}$$ medium in a HNO$$_{3}$$/supercritical CO$$_{2}$$-tributyl phosphate system

Meguro, Yoshihiro; ; Yoshida, Zenko

Analytical Chemistry, 70(7), p.1262 - 1267, 1998/00

 Times Cited Count:52 Percentile:85.95(Chemistry, Analytical)

no abstracts in English

Journal Articles

Pressure-dependence of extraction equilibrium of uranium and plutonium ions in a HNO$$_{3}$$/supercritical CO$$_{2}$$-tributyl phosphate system

Meguro, Yoshihiro; ; *; Takeishi, Hideyo; Sasaki, Takayuki*; Yoshida, Zenko

Proc. of Int. Trace Analysis Symp. '98 (ITAS'98), p.25 - 26, 1998/00

no abstracts in English

Journal Articles

Extraction of uranium(VI) in nitric acid solution with supercritical carbon dioxide fluid containing tributylphosphate

Meguro, Yoshihiro; ; Takeishi, Hideyo; Yoshida, Zenko

Radiochimica Acta, 75(4), p.185 - 191, 1996/00

no abstracts in English

Journal Articles

Extraction of Uranium(VI) from nitric acid solution to supercritical carbon dioxide containing Tri-n-butylphosphate

; Meguro, Yoshihiro; Yoshida, Zenko

Chemistry Letters, 0(5), p.365 - 366, 1995/00

no abstracts in English

14 (Records 1-14 displayed on this page)
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